I think guest is right but I think Dolly Parton also did a version of Boulder to Birmingham.
What Female Singer With Big Blonde Curly Hair Sang A Song With Birmingham In The Title?
Amanda Marshall
A 70's song named FIRE I think a female sings it
I was able to find a country song called boulder to birmingham by emmylou harris... Not sure if she has big curly blonde though.... Its blonde, though